Nitrogen isotope evidence for stepwise oxygenation of the ocean during the Great Oxidation Event

{The Earth's oxygenation represents one of the most important environmental drivers of life's evolution, with the first rise, known as `the Great Oxidation Event' (GOE), corresponding to unpreceded accumulation of atmospheric O-2, changes in the flux of marine nutrients and possibly global glaciations. However, the detailed evolution of the GOE is still debated, as for instance the accumulation trends of oceanic versus atmospheric oxygen and the nature of biogeochemical responses to oxygenation. Here, we combine organic carbon and bulk nitrogen isotope compositions with major element concentrations and iron speciation data of sedimentary rocks recovered from two drill cores (T2 and T3) in the early Paleoproterozoic Turee Creek Group, Western Australia, to track the redox evolution of marine conditions during the GOE. T2 core samples of the Kungarra Formation, which consists of elastic sedimentary rocks overlaid by the glaciogenic Meteorite Bore Member, were deposited similar to 2.31 Ga ago. T3 core intercepts, from bottom to top, quartzite of the Koolbye Formation, and shales and stromatolitic carbonates of the Kazput Formation, which were deposited around similar to 2.25 Ga. Samples from T2 show minor variations of delta C-13(org) (avg. -34.5 +/- 1.7%e