A sterically congested 1,2-diphosphino-1 `-boryl-ferrocene: synthesis, characterization and coordination to platinum
| Affiliation auteurs | !!!! Error affiliation !!!! |
| Titre | A sterically congested 1,2-diphosphino-1 `-boryl-ferrocene: synthesis, characterization and coordination to platinum |
| Type de publication | Journal Article |
| Year of Publication | 2019 |
| Auteurs | Lerayer E, Renaut P, Roger J, Pirio N, Cattey H, Fleurat-Lessard P, Boudjelel M, Massou S, Bouhadir G, Bourissou D, Hierso J-C |
| Journal | DALTON TRANSACTIONS |
| Volume | 48 |
| Pagination | 11191-11195 |
| Date Published | AUG 14 |
| Type of Article | Article |
| ISSN | 1477-9226 |
| Résumé | A new class of tritopic ferrocene-based ambiphilic compounds has been prepared by assembling diphosphino- and boryl-substituted cyclopentadienides at iron. The presence of five sterically demanding substituents on the ferrocene platform induces conformational constraints, as is apparent from XRD and NMR data, but does not prevent the chelating coordination to platinum. The Lewis acid moiety is pendant in both the free ligand and the platinum complex. |
| DOI | 10.1039/c9dt01921a |