Triterpenoid Saponins From the Stem Bark of Pentaclethra eetveldeana

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TitreTriterpenoid Saponins From the Stem Bark of Pentaclethra eetveldeana
Type de publicationJournal Article
Year of Publication2019
AuteursPertuit D, Kapundu M, Mitaine-Offer A-C, Miyamoto T, Tanaka C, Delaude C, Lacaille-Dubois M-A
JournalNATURAL PRODUCT COMMUNICATIONS
Volume14
Date PublishedJUL
Type of ArticleArticle
ISSN1934-578X
Mots-clés2D NMR, Fabaceae, MS, Pentaclethra eetveldeana, Triterpene saponins
Résumé

Two previously undescribed triterpenoid saponins together with 4 known ones were isolated from the stem bark of Pentaclethra eetveldeana De Wild. & Th. Dur. Their structures were elucidated by spectroscopic methods including 1D and 2D NMR experiments in combination with mass spectrometry as 3-O-beta-D-glucopyranosyl-(1 -> 2)-[beta-D-glucopyranosyl-(1 -> 3)]-beta-D-glucopyranosyl-(1 -> 4)-beta-D-glucopyranosyl-(1 -> 3)-alpha-L-rhamnopyranosyl-(1 -> 2)-[beta-D-glucopyranosyl-(1 -> 4)]-alpha-L-arabinopyranosyloleanolic acid and 3-O-beta-D-glucopyranosyl-(1 -> 2)-[beta-D-glucopyranosyl-(1 -> 3)]-beta-D-glucopyranosyl-(1 -> 4)-beta-D-glucopyranosyl-(1 -> 3)-alpha-L-rhamnopyranosyl-(1 -> 2)-[beta-D-glucopyranosyl-(1 -> 4)]-alpha-L-arabinopyranosylhederagenin.

DOI10.1177/1934578X19863947