1,3-Dithianes as Assembling Ligands for the Construction of Copper(I) Coordination Polymers. Investigation of the Impact of the RC(H)S2C3H6 Substituent and Reaction Conditions on the Architecture of the 0D-3D Networks
| Affiliation auteurs | !!!! Error affiliation !!!! |
| Titre | 1,3-Dithianes as Assembling Ligands for the Construction of Copper(I) Coordination Polymers. Investigation of the Impact of the RC(H)S2C3H6 Substituent and Reaction Conditions on the Architecture of the 0D-3D Networks |
| Type de publication | Journal Article |
| Year of Publication | 2019 |
| Auteurs | Raghuvanshi A, Knorr M, Knauer L, Strohmann C, Boullanger S, Moutarlier V, Viau L |
| Journal | INORGANIC CHEMISTRY |
| Volume | 58 |
| Pagination | 5753-5775 |
| Date Published | MAY 6 |
| Résumé | {The parent compound 1,3-dithiane (LI) was reacted with CuI providing the 1D coordination polymer [{Cu(mu(2)-I)(2)Cu}-(mu(2) -L1)(2)](n) (CP1 ), an isostructural compound [{Cu(mu(2)-Br)(2)Cu}(mu(2)-L1)(2) (CP2) was isolated upon treatment of CuBr with LI. In contrast, treatment of LI with CuCl results in the formation of 2D polymeric [{Cu(mu(2)-Cl)(2)Cu}(mu(2)-L1)](n) (CP3), in which each sulfur atom acts as a 4-electron donor. The ID compounds [{Cu(mu(2)-X) 2Cu}(mu(2)-L2)(2)](n) (CP7 |