Hydrogenolysis of carbon-carbon sigma-bonds using water catalysed by semi-rigid diiridium(iii) porphyrins
| Affiliation auteurs | !!!! Error affiliation !!!! |
| Titre | Hydrogenolysis of carbon-carbon sigma-bonds using water catalysed by semi-rigid diiridium(iii) porphyrins |
| Type de publication | Journal Article |
| Year of Publication | 2019 |
| Auteurs | Fong CWai, Yu HYin, Gros CP, Chan KShing |
| Journal | NEW JOURNAL OF CHEMISTRY |
| Volume | 43 |
| Pagination | 3656-3659 |
| Date Published | MAR 7 |
| Type of Article | Article |
| ISSN | 1144-0546 |
| Résumé | Semi-rigid diiridium(III) porphyrin alkyls with m-xylyl and p-xylyl diether linkers were synthesized. They were found to be catalysts for the carbon-carbon r-bond hydrogenolysis of [2.2] paracyclophane under neutral conditions using water as the hydrogen source. The ether linkages in semi-rigid diiridium(III) porphyrins are unstable and undergo cleavage during the reaction. |
| DOI | 10.1039/c8nj05664a |