Effect of spinel and perovskite coatings on the long term oxidation of a ferritic stainless steel in H-2/H2O atmosphere

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TitreEffect of spinel and perovskite coatings on the long term oxidation of a ferritic stainless steel in H-2/H2O atmosphere
Type de publicationJournal Article
Year of Publication2019
AuteursArdigo-Besnard M.R, Popa I., Chevalier S.
JournalCORROSION SCIENCE
Volume148
Pagination251-263
Date PublishedMAR
Type of ArticleArticle
ISSN0010-938X
Mots-clésHigh temperature corrosion, Oxidation, Oxide coatings, SEM, Stainless steel, X-ray diffraction
Résumé

In order to improve the oxidation behaviour of AISI441 ferritic stainless steel in H-2/H2O atmosphere at 800 degrees C, four oxide coatings were tested: two perovskites (La0.8Sr0.2MnO3 and LaNi0.6Fe0.4O3) deposited by screen printing and two spinels (MnCo2O4 and Co3O4) obtained by PVD technique. Isothermal oxidation tests performed up to 3000 h showed that the coating presence avoided Fe oxides growth, which occurs for the raw alloy in the same conditions. Moreover, a protective (Cr,Mn)(3)O-4/Cr2O3 layer formed between the substrate and the coating. Any presence of Cr was not detected within the coatings, indicating that all compositions were efficient in preventing Cr evaporation.

DOI10.1016/j.corsci.2018.12.034