s-Block metal scorpionates - A new sodium hydrido-tris(3,5-dimethyl-1-pyrazolyl)borate salt showing an unusual core stabilized by bridging and terminal O-bonded DMSO ligands
| Affiliation auteurs | !!!! Error affiliation !!!! |
| Titre | s-Block metal scorpionates - A new sodium hydrido-tris(3,5-dimethyl-1-pyrazolyl)borate salt showing an unusual core stabilized by bridging and terminal O-bonded DMSO ligands |
| Type de publication | Journal Article |
| Year of Publication | 2020 |
| Auteurs | Plasseraud L, Cattey H |
| Journal | MAIN GROUP METAL CHEMISTRY |
| Volume | 43 |
| Pagination | 102-110 |
| Date Published | JAN |
| Type of Article | Article |
| ISSN | 0792-1241 |
| Mots-clés | 5-dimethylpyrazol-1-yl)borate, Crystal structure, DMSO coordination, hydrido-tris(3, sodium |
| Résumé | {Dissolution of [(mu-Me2CO)(3)(NaTp*)(2)] (1) (Tp* = hydrido-tris(3,5-dimethyl-1-pyrazolyl)borate) in DMSO at room temperature leads to the growth of colourless crystals characterized as the new salt [Na(2)Tp*(mu-Me2SO)(3)(Me2SO)(3)] [NaTp*(2)] (2). 2 crystallized in the trigonal space group R3 with Z = 3 |
| DOI | 10.1515/mgmc-2020-0012 |