Crystal structure of dicarbonyl[mu(2)-methylenebis-(diphenylphosphane)-kappa P-2:P `][mu(2)-2-(2,4,5-trimethyl-phenyl)-3-oxoprop-1-ene-1,3-diyl](trinheny l-phosnhane-kappa P)ironplatinum(Fe-Pt)-dichloro-metnane-toluene (1/1/2), [(OC)(2)Fe(mu-dppm)(mu-C(=O
| Affiliation auteurs | !!!! Error affiliation !!!! |
| Titre | Crystal structure of dicarbonyl[mu(2)-methylenebis-(diphenylphosphane)-kappa P-2:P `][mu(2)-2-(2,4,5-trimethyl-phenyl)-3-oxoprop-1-ene-1,3-diyl](trinheny l-phosnhane-kappa P)ironplatinum(Fe-Pt)-dichloro-metnane-toluene (1/1/2), [(OC)(2)Fe(mu-dppm)(mu-C(=O |
| Type de publication | Journal Article |
| Year of Publication | 2019 |
| Auteurs | Brieger L, Jourdain I, Knorr M, Strohmann C |
| Journal | ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS |
| Volume | 75 |
| Pagination | 1902+ |
| Date Published | DEC |
| Type of Article | Article |
| ISSN | 2056-9890 |
| Mots-clés | bis(diphenyl-phosphino)methane, C-H center dot center dot center dot pi interactions, Crystal structure, heterobimetallic, hydrogen bonding, Iron, metal-metal bond dimetallacyclopentenone, Platinum, terminal alkyne |
| Résumé | The title compound, [FePt(C12H12O)(C18H15P)(C25H22P2)(CO)(2)]center dot 2C(7)H(8)-CH2 Cl-2 or [(OC)(2)Fe(mu-dppm)(mu-C(=O)C(2,4,5-C6H2Me3)=CH)Pt(PPh3)], represents an example of a diphosphane-bridged heterobimetallic dimetallacyclopentenone complex resulting from a bimetallic activation of 1-ethynyl-2,4,5-trimethylbenzene and a metal-coordinated carbonyl ligand. The bridging mu(2)-C(=O)C(2,4,5-C6H2Me3)=CH unit (stemming from a carbon-carbon coupling reaction between CO and the terminal alkyne) forms a five-membered dimetallacyclopentenone ring, in which the C=C bond is pi-coordinated to the Fe centre. The latter is connected to the Pt centre through a short metal-metal bond of 2.5770 (5) angstrom. In the crystal, the complex is solvated by one dichloromethane and two toluene molecules. |
| DOI | 10.1107/S2056989019015573 |