Oxidative C-N fusion of pyridinyl-substituted porphyrins
| Affiliation auteurs | !!!! Error affiliation !!!! |
| Titre | Oxidative C-N fusion of pyridinyl-substituted porphyrins |
| Type de publication | Journal Article |
| Year of Publication | 2018 |
| Auteurs | Berthelot M, Hoffmann G, Bousfiha A, Echaubard J, Roger J, Cattey H, Romieu A, Lucas D, Fleurat-Lessard P, Devillers CH |
| Journal | CHEMICAL COMMUNICATIONS |
| Volume | 54 |
| Pagination | 5414-5417 |
| Date Published | MAY 28 |
| Type of Article | Article |
| ISSN | 1359-7345 |
| Résumé | The mild (electro) chemical oxidation of pyridin-2-ylthio-meso substituted Ni(II) porphyrins affords C-N fused cationic and dicationic pyridinium-based derivatives. These porphyrins are fully characterized and the molecular structure of one of them was confirmed by X-ray crystallography. A mechanism for the intramolecular oxidative C-N coupling is proposed based on theoretical calculations and cyclic voltammetry analyses. |
| DOI | 10.1039/c8cc01375f |