Quantum dynamics of O-16 in collision with ortho- and para-(OO)-O-17-O-17
Affiliation auteurs | !!!! Error affiliation !!!! |
Titre | Quantum dynamics of O-16 in collision with ortho- and para-(OO)-O-17-O-17 |
Type de publication | Journal Article |
Year of Publication | 2017 |
Auteurs | Guillon G, Honvault P |
Journal | CHEMICAL PHYSICS LETTERS |
Volume | 689 |
Pagination | 62-67 |
Date Published | DEC 1 |
Type of Article | Article |
ISSN | 0009-2614 |
Mots-clés | Collision rates, Isotope effect, Nuclear spin isomers, Quantum reactive scattering |
Résumé | We report full quantum dynamical observables, such as integral and differential cross sections and rate constants, for the O-16 + (OO)-O-17-O-17 reactive collision process. We particularly emphasize the effect coming from the nonzero nuclear spin of O-17, leading to two nuclear spin isomers of O-34(2), ortho-and para-O-34(2) which can be studied independently and behave differently. A comparison with the O-16 + (OO)-O-18-O-18 collision is given. We find that processes involving (OO)-O-17-O-17 are always faster than with (OO)-O-18-O-18. (C) 2017 Elsevier B.V. All rights reserved. |
DOI | 10.1016/j.cplett.2017.09.063 |