Study of titanium alloy Ti6242S oxidation behaviour in air at 560 degrees C: Effect of oxygen dissolution on lattice parameters

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TitreStudy of titanium alloy Ti6242S oxidation behaviour in air at 560 degrees C: Effect of oxygen dissolution on lattice parameters
Type de publicationJournal Article
Year of Publication2020
AuteursBerthaud M., Popa I., Chassagnon R., Heintz O., Lavkova J., Chevalier S.
JournalCORROSION SCIENCE
Volume164
Pagination108049
Date PublishedMAR
Type of ArticleArticle
ISSN0010-938X
Mots-clésAlloy, High temperature corrosion, TEM, Titanium, X-ray diffraction
Résumé

High temperature oxidation of titanium alloy Ti6242S was studied in air at 560 degrees C up to 10000 h. Oxidation kinetics obeys a parabolic law (k(p) = 8.7 x 10(-15) g(2). cm(-4).s(-1)). Oxygen dissolution in the metal was found to represent between 80 and 90% of the total mass gain. Thin oxide scales are mainly composed of TiO2, in top of which some alumina is present. Titanium nitride was detected as a very thin layer at the outer part of the metallic substrate. Underneath, the oxygen dissolution area was found to reach the maximum brittleness after 1000 h of oxidation.

DOI10.1016/j.corsci.2019.06.004