Electroactive Composite Pd-Polypyrrole and Its Catalytic Properties in the Reaction of Styryl Bromide Cyanation
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Titre | Electroactive Composite Pd-Polypyrrole and Its Catalytic Properties in the Reaction of Styryl Bromide Cyanation |
Type de publication | Journal Article |
Year of Publication | 2018 |
Auteurs | Nikitin O.M, Magdesieva T.V, Polyakova O.V, Sazonov P.K, Gor'kov K.V, Zolotukhina E.V, Vorotyntsev M.A |
Journal | RUSSIAN JOURNAL OF ELECTROCHEMISTRY |
Volume | 54 |
Pagination | 608-611 |
Date Published | JUL |
Type of Article | Article |
ISSN | 1023-1935 |
Mots-clés | cyclic voltammetry, Cycling, electroactivity, Nanocomposite, Palladium, styryl bromide |
Résumé | A composite material in the form of powder is synthesized by a redox reaction in mixed aqueous solution of Pd(NH3)(4)Cl-2 + pyrrole. The composite consists of polypyrrole globules with palladium nanoparticles uniformly distributed inside the latter. Being applied as a film on the electrode surface, both components of this material exhibit redox activity. Palladium particles inside the composite exhibit catalytic properties in cyanation of styryl bromides, a reaction widely used in fine organic synthesis. |
DOI | 10.1134/S1023193518070066 |