Synthesis, characterization, and thermal properties of N, N, N `, N `-tetramethyl guanidinium tribromidocadmate(II) exhibiting an unusual coordination geometry

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TitreSynthesis, characterization, and thermal properties of N, N, N `, N `-tetramethyl guanidinium tribromidocadmate(II) exhibiting an unusual coordination geometry
Type de publicationJournal Article
Year of Publication2017
AuteursNdiaye M, Samb A, Diop L, Cattey H, Pourchet S, Plasseraud L
JournalMAIN GROUP METAL CHEMISTRY
Volume40
Pagination137-143
Date PublishedDEC
Type of ArticleArticle
ISSN0792-1241
Mots-clésbromocadmate(II), Differential scanning calorimetry, N-H center dot center dot center dot Br interaction, organic-inorganic hybrid materials, Thermogravimetric analysis, X-ray crystallography
Résumé

{The reaction of N, N, N', N'-tetramethyl guanidine, NHC(N(CH3)(2))(2) (TMGD) and CdBr2 center dot 4H(2)O in ethanol led to the formation of [TMGDH][CdBr3] (1), which crystallizes in the monoclinic space group Cc with Z = 4

DOI10.1515/mgmc-2017-0028