Synthesis, spectroscopic, cyclic voltammetry properties and molecular structure of the thiocyanato-N meso-tetratolylporphyrinato zinc(II) ion complex
| Affiliation auteurs | !!!! Error affiliation !!!! |
| Titre | Synthesis, spectroscopic, cyclic voltammetry properties and molecular structure of the thiocyanato-N meso-tetratolylporphyrinato zinc(II) ion complex |
| Type de publication | Journal Article |
| Year of Publication | 2017 |
| Auteurs | Denden Z, Harhouri W, Hassen LBen Haj, Rousselin Y, Saint-Aman E, Nasri H |
| Journal | JOURNAL OF MOLECULAR STRUCTURE |
| Volume | 1133 |
| Pagination | 472-478 |
| Date Published | APR 5 |
| Type of Article | Article |
| ISSN | 0022-2860 |
| Mots-clés | cyclic voltammetry, UV-visible, X-ray diffraction, Zinc porphyrin complex |
| Résumé | {This paper describes the synthesis of the (thiocyanato-N)(meso-tetratolylporphyrinato)zinc(II) chlorobenzene monosolvate complex with the formula [K(2,2,2-crypt)][Zn(TTP)(NCS)].C6H5Cl (I) using the cryptand-222 to solubilize potassium thiocyanate in chlorobenzene solvent. Complex (I) has been characterized by elementary analysis, IR, UV vis, H-1 NMR and MS, and the structure of this new zinc(II) metalloporphyrin been examined crystallographically. A cyclic voltammetry investigation was also carried out on this species. The title compound crystallizes in the triclinic, space group P-1, with a = 11.5151(7) angstrom |
| DOI | 10.1016/j.molstruc.2016.11.080 |