The Stereoselective Self-Assembly of Chiral Metallo-Organic Cryptophanes
Affiliation auteurs | !!!! Error affiliation !!!! |
Titre | The Stereoselective Self-Assembly of Chiral Metallo-Organic Cryptophanes |
Type de publication | Journal Article |
Year of Publication | 2016 |
Auteurs | Schaly A, Rousselin Y, Chambron J-C, Aubert E, Espinosa E |
Journal | EUROPEAN JOURNAL OF INORGANIC CHEMISTRY |
Pagination | 832-843 |
Date Published | FEB |
Type of Article | Article |
ISSN | 1434-1948 |
Mots-clés | Cage compounds, chirality, Cryptophanes, N ligands, Palladium, Self-assembly |
Résumé | {Cryptophanes are macropolycyclic cyclophanes constructed from two triply bridged concave cyclotriveratrylene analogues that encapsulate a large range of molecular and monoatomic substrates. Self-assembled metallo-organic cryptophanes based on M2+-carbonitrile (M = Pd or Pt) interactions have been obtained through the reactions of chiral nitrile-substituted cyclotribenzylenes (CTBs) 1 and 2 with [M(dppp)][OTf](2) (dppp = 1,3-bisdiphenylphosphinopropane |
DOI | 10.1002/ejic.201501446 |