The Stereoselective Self-Assembly of Chiral Metallo-Organic Cryptophanes

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TitreThe Stereoselective Self-Assembly of Chiral Metallo-Organic Cryptophanes
Type de publicationJournal Article
Year of Publication2016
AuteursSchaly A, Rousselin Y, Chambron J-C, Aubert E, Espinosa E
JournalEUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Pagination832-843
Date PublishedFEB
Type of ArticleArticle
ISSN1434-1948
Mots-clésCage compounds, chirality, Cryptophanes, N ligands, Palladium, Self-assembly
Résumé

{Cryptophanes are macropolycyclic cyclophanes constructed from two triply bridged concave cyclotriveratrylene analogues that encapsulate a large range of molecular and monoatomic substrates. Self-assembled metallo-organic cryptophanes based on M2+-carbonitrile (M = Pd or Pt) interactions have been obtained through the reactions of chiral nitrile-substituted cyclotribenzylenes (CTBs) 1 and 2 with [M(dppp)][OTf](2) (dppp = 1,3-bisdiphenylphosphinopropane

DOI10.1002/ejic.201501446