Direct P-functionalization of azobenzene by a cationic phosphidozirconocene complex
| Affiliation auteurs | !!!! Error affiliation !!!! |
| Titre | Direct P-functionalization of azobenzene by a cationic phosphidozirconocene complex |
| Type de publication | Journal Article |
| Year of Publication | 2016 |
| Auteurs | Normand AT, Daniliuc CG, Kehr G, Le Gendre P, Erker G |
| Journal | DALTON TRANSACTIONS |
| Volume | 45 |
| Pagination | 3711-3714 |
| Type of Article | Article |
| ISSN | 1477-9226 |
| Résumé | We report that the cationic phosphidozirconocene complex [(eta(5)-C5H5)(2)Zr(PCy2)][CH3B(C6F5)(3)] (II) reacts with azobenzene, resulting in the expedient formation of Zr complex (2) bound to a tridentate PNN ligand. This reaction proceeds by a mechanism of cooperative nucleophilic substitution of hydrogen. The intermediate sigma(H) adduct (1) has been characterized by NMR spectroscopy. |
| DOI | 10.1039/c6dt00416d |