Regioselective C-H amination of free base porphyrins via electrogenerated pyridinium-porphyrins and stabilization of easily oxidized amino-porphyrins by protonation
| Affiliation auteurs | !!!! Error affiliation !!!! |
| Titre | Regioselective C-H amination of free base porphyrins via electrogenerated pyridinium-porphyrins and stabilization of easily oxidized amino-porphyrins by protonation |
| Type de publication | Journal Article |
| Year of Publication | 2020 |
| Auteurs | Bousfiha A, Dime AKD, Mankou-Makaya A, Echaubard J, Berthelot M, Cattey H, Romieu A, Roger J, Devillers CH |
| Journal | CHEMICAL COMMUNICATIONS |
| Volume | 56 |
| Pagination | 884-887 |
| Date Published | JAN 18 |
| Type of Article | Article |
| ISSN | 1359-7345 |
| Résumé | Four free base aminoporphyrins were synthesized in two steps via regioselective anodic nucleophilic substitution with pyridine followed by ring opening of the electrogenerated pyridinium with piperidine. The X-ray crystallographic structure of the unstable 2-aminotetraphenylporphyrin was solved. Protonation of this latter compound leads to the stable diiminium porphyrin salt. |
| DOI | 10.1039/c9cc07351e |