Application of isotopic tracers as a tool for understanding hydrodynamic behavior of the highly exploited Diass aquifer system (Senegal)

The Diass horst aquifer system located 50 km east of Dakar (Senegal) is exploited in two main aquifers covered by a sandy superficial aquifer: the confined/unconfined Palaeocene karstic limestone and the confined Maastrichtian sandstone aquifer underneath. This system has experienced intensive groundwater abstraction during the last 50 years to supply increasing water demand, agricultural and industrial needs. The high abstraction rate from 1989 to 2009 (about 109,000 m(3)/d) has caused a continuous groundwater level decline (up to 30 m), a modification of the groundwater flow and salinization in parts of the aquifers. The objective of the study is to improve our understanding of the system functioning with regards to high pumping, identify the geochemical reactions that take place in the system, infer origin and timing of recharge by using mainly stable (delta O-18, delta 2H, 13C) and radioactive (H-3 and C-14) isotopes. Water types defined in the Piper diagram vary in order of abundance from Ca-HCO3 (65%), Ca/Na-CI (20%), Na-HCO3 (3%) and Na-CI (12%). Values of delta(18O) and delta H-2 for the superficial aquifer range between - 5.8 and -4.2%,, and between -42 and -31Too, respectively. For the Palaeocene aquifer they range from -5.8 to -5.0% and from -38 to -3170o, respectively; values in the Maastrichtian aquifer are between - 5.9 and -4.3%0 for 5180 and -38 to -26%0 for 52H. Plotted against the conventional 5180 vs 82H diagram, data from the upper aquifer exhibit a dispersed distribution with respect to isotopic fractionation while those of the Palaeocene and Maastrichtian aquifers are aligned parallel and slightly below/or on the Global Meteoric Water Line (GMWL) evidencing ancient waters which had evaporated during infiltration. The low tritium (generally <0.7 TU) and C-14 (0.7-57.2 pmc) contents indicate predominance of older water being recharged during the Pleistocene and Holocene periods. However, few boreholes which exhibit high tritium (1.2-4.3 TU) and C-14 (65.7-70.8 pmc) values indicate some mixture with recent water likely through faulting and vertical drainage from the upper to deeper aquifers as well as lateral flow along flow paths to the piezometric depressions created by pumping. (C) 2014 Elsevier B.V. All rights reserved.