Synthesis of P-Chirogenic Diphosphinotriazoles and Their Use in Asymmetric Catalysis
| Affiliation auteurs | !!!! Error affiliation !!!! |
| Titre | Synthesis of P-Chirogenic Diphosphinotriazoles and Their Use in Asymmetric Catalysis |
| Type de publication | Journal Article |
| Year of Publication | 2021 |
| Auteurs | Bayardon J, Rousselin Y, Malacea-Kabbara R |
| Journal | CHEMISTRYSELECT |
| Volume | 6 |
| Pagination | 2687-2691 |
| Date Published | MAR 19 |
| Type of Article | Article |
| ISSN | 2365-6549 |
| Mots-clés | Asymmetric allylic substitution, P, P-chirogenic diphosphine, P-ligand, Palladium |
| Résumé | The stereoselective synthesis of P-chirogenic diphosphinotriazoles using ephedrine methodology was described. The coordination behavior of these compounds as P,P-ligands has been demonstrated by the preparation as well as the spectroscopic and X-ray crystallographic analyses of a palladium complex. The efficiency of these new P-chirogenic diphosphines in the palladium-catalyzed asymmetric allylic substitution reaction was also evaluated. |
| DOI | 10.1002/slct.202100617 |