A 5-(difluorenyl)-1,10-phenanthroline- based Ru( II) complex as a coating agent for potential multifunctional gold nanoparticles
| Affiliation auteurs | !!!! Error affiliation !!!! |
| Titre | A 5-(difluorenyl)-1,10-phenanthroline- based Ru( II) complex as a coating agent for potential multifunctional gold nanoparticles |
| Type de publication | Journal Article |
| Year of Publication | 2014 |
| Auteurs | Moreau J, Lux F, Four M, Olesiak-Banska J, Matczyszyn K, Perriat P, Frochot C, Arnoux P, Tillement O, Samoc M, Ponterini G, Roux S, Lemercier G |
| Journal | PHYSICAL CHEMISTRY CHEMICAL PHYSICS |
| Volume | 16 |
| Pagination | 14826-14833 |
| Type of Article | Article |
| ISSN | 1463-9076 |
| Résumé | The synthesis and photophysical properties of small gold nanoparticles (NPs, AuNP-[Ru-PFF]) surface functionalized by 5-substituted-1,10-phenanthroline-ligand based Ru(II) complexes are described. Luminescence of the grafted and confined Ru(II) complexes is totally quenched on the gold surface. Nonlinear optical properties were determined via Z-scan measurements in the range 600-1300 nm for both the free Ru(II) complex and the related NPs. In the short wavelength range (around 600 nm) the behaviour switches from that of two-photon absorption (2PA) for the complex to saturable absorption for the NPs. 2PA applications such as optical power limiting or two-photon dioxygen sensitization can be anticipated for these nanoplatforms. |
| DOI | 10.1039/c4cp01534g |