Ditopic Macrocyclic Receptors with a 4,7-Diamino-1,10-phenanthroline Fragment for Multimodal Detection of Toxic Metal Ions
| Affiliation auteurs | !!!! Error affiliation !!!! |
| Titre | Ditopic Macrocyclic Receptors with a 4,7-Diamino-1,10-phenanthroline Fragment for Multimodal Detection of Toxic Metal Ions |
| Type de publication | Journal Article |
| Year of Publication | 2016 |
| Auteurs | Abel AS, Mitrofanov AYu., Rousselin Y, Denat F, Bessmertnykh-Lemeune A, Averin AD, Beletskaya IP |
| Journal | CHEMPLUSCHEM |
| Volume | 81 |
| Pagination | 35-39 |
| Date Published | JAN |
| Type of Article | Article |
| ISSN | 2192-6506 |
| Mots-clés | amination, Cross-coupling, Macrocyclic ligands, Palladium, Sensors |
| Résumé | A series of ditopic macrocyclic receptors with variable cavity sizes, containing nitrogen or mixed (nitrogen-oxygen) donor sites and an externally directed 1,10-phenanthroline fragment, were prepared by means of a palladium-catalyzed amination reaction. A ditopic mixed NO-ligand (4a) was coordinated to [Ru(bpy)(2)](2+) (bpy=2,2-bipyridine) to prepare a luminescent and chromogenic complex, [Ru(bpy)(2)(4a)][PF](2), which provided the selective dual-channel detection of Cu-II ions. |
| DOI | 10.1002/cplu.201500390 |