Efficient energy transfer in a tri-chromophoric dyad containing BODIPYs and corrole based on a truxene platform

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TitreEfficient energy transfer in a tri-chromophoric dyad containing BODIPYs and corrole based on a truxene platform
Type de publicationJournal Article
Year of Publication2018
AuteursYang J, Cai F-J, Yuan X-M, Meng T, Xin G-X, Wang S-F, Gros CP, Xu H-J
JournalJOURNAL OF PORPHYRINS AND PHTHALOCYANINES
Volume22
Pagination777-783
Date PublishedSEP-OCT
Type of ArticleArticle
ISSN1088-4246
Mots-clésBODIPY, corrole, energy transfer, truxene
Résumé

A star-shaped molecule was designed and synthesized based on a known central truxene platform. Two BODIPY derivatives and one corrole macrocycle were introduced and connected to the 2, 7 and 12-positions of the truxene unit by Suzuki coupling. The dyad was fully characterized by UV-vis absorption, proton nuclear magnetic resonance, mass spectrometry. The direction of energy transfer upon electronic excitation was explored, and the star-shaped molecule system exhibits a highly efficient photoinduced energy transfer process from the excited BODIPY part to the corrole unit.

DOI10.1142/S108842461850058X