Coordination RC6H4S(CH2)(8)SC6H4R/(CuI)(n) Polymers (R (n) = H (4); Me (8)): An Innocent Methyl Group that Makes the Difference
| Affiliation auteurs | !!!! Error affiliation !!!! |
| Titre | Coordination RC6H4S(CH2)(8)SC6H4R/(CuI)(n) Polymers (R (n) = H (4); Me (8)): An Innocent Methyl Group that Makes the Difference |
| Type de publication | Journal Article |
| Year of Publication | 2015 |
| Auteurs | Harvey PD, Bonnot A, Lapprand A, Strohmann C, Knorr M |
| Journal | MACROMOLECULAR RAPID COMMUNICATIONS |
| Volume | 36 |
| Pagination | 654-659 |
| Date Published | APR |
| Type of Article | Article |
| ISSN | 1022-1336 |
| Mots-clés | clusters, coordination polymers, Copper, Dithioether, Luminescence |
| Résumé | Under identical conditions, CuI reacts with PhS(CH2)(8)SPh and p-TolS(CH2)(8)STol-p affording, respectively, a luminescent 1D coordination polymer [Cu4I4{(2)-PhS(CH2)(8)SPh}(2)](n) (1) and an unprecedented 2D network [Cu8I8{(2)-p-TolS(CH2)(8)STol-p}(3)(MeCN)(2)](n) (2), which incorporate closed-cubane Cu4I4 and octanuclear Cu8I8 clusters of as connecting nodes. Their thermal and photophysical properties exhibit notable differences. |
| DOI | 10.1002/marc.201400659 |