Cu(I) complexes with diethoxyphosphoryl-1,10-phenanthrolines in catalysis of C-C and C-heteroatom bonds formation
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Titre | Cu(I) complexes with diethoxyphosphoryl-1,10-phenanthrolines in catalysis of C-C and C-heteroatom bonds formation |
Type de publication | Journal Article |
Year of Publication | 2015 |
Auteurs | A. Mitrofanov Y, Bessmertnykh-Lemeune A.G, Beletskaya I.P |
Journal | INORGANICA CHIMICA ACTA |
Volume | 431 |
Pagination | 297-301 |
Date Published | MAY 24 |
Type of Article | Article |
ISSN | 0020-1693 |
Mots-clés | Cu-catalysis, Formation of C-C and C-heteroatom bonds, Phosphorylated phenanthrolines |
Résumé | Diethoxyphosphoryl substituted 1,10-phenanthroline copper(I) complexes were tested as catalysts in the Sonogashira-type reaction, alpha-arylation of phosphoryl-stabilized C-H acids, C-N, C-P bond forming reactions (substitution reactions) and in the reaction of phenylacetylene and bis(pinacolato) diboron (addition reaction). The complexes demonstrate fairly high catalytic activity and in some cases their efficiency is superior to that of the parent Cu(phen)(PPh3)Br (phen = phenanthroline). (C) 2015 Elsevier B.V. All rights reserved. |
DOI | 10.1016/j.ica.2015.04.004 |