Cu(I) complexes with diethoxyphosphoryl-1,10-phenanthrolines in catalysis of C-C and C-heteroatom bonds formation

Affiliation auteurs!!!! Error affiliation !!!!
TitreCu(I) complexes with diethoxyphosphoryl-1,10-phenanthrolines in catalysis of C-C and C-heteroatom bonds formation
Type de publicationJournal Article
Year of Publication2015
AuteursA. Mitrofanov Y, Bessmertnykh-Lemeune A.G, Beletskaya I.P
JournalINORGANICA CHIMICA ACTA
Volume431
Pagination297-301
Date PublishedMAY 24
Type of ArticleArticle
ISSN0020-1693
Mots-clésCu-catalysis, Formation of C-C and C-heteroatom bonds, Phosphorylated phenanthrolines
Résumé

Diethoxyphosphoryl substituted 1,10-phenanthroline copper(I) complexes were tested as catalysts in the Sonogashira-type reaction, alpha-arylation of phosphoryl-stabilized C-H acids, C-N, C-P bond forming reactions (substitution reactions) and in the reaction of phenylacetylene and bis(pinacolato) diboron (addition reaction). The complexes demonstrate fairly high catalytic activity and in some cases their efficiency is superior to that of the parent Cu(phen)(PPh3)Br (phen = phenanthroline). (C) 2015 Elsevier B.V. All rights reserved.

DOI10.1016/j.ica.2015.04.004