Synthesis, Electrochemistry, and Photophysics of Aza-BODIPY Porphyrin Dyes

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TitreSynthesis, Electrochemistry, and Photophysics of Aza-BODIPY Porphyrin Dyes
Type de publicationJournal Article
Year of Publication2016
AuteursPascal S, Bucher L, Desbois N, Bucher C, Andraud C, Gros CP
JournalCHEMISTRY-A EUROPEAN JOURNAL
Volume22
Pagination4971-4979
Date PublishedMAR 24
Type of ArticleArticle
ISSN0947-6539
Mots-clésaza-BODIPYs, Electrochemistry, fluorescence spectroscopy, photoinduced electron transfer, polyads, Porphyrinoids
Résumé

The synthesis of dyad and triad aza-BODIPY-porphyrin systems in two steps starting from an aryl-substituted aza-BODIPY chromophore is described. The properties of the resulting aza-BODIPY-porphyrin conjugates have been extensively investigated by means of electrochemistry, spectroelectrochemistry, and absorption/emission spectroscopy. Fluorescence measurements have revealed a dramatic loss of luminescence intensity, mainly due to competitive energy transfer and photoinduced electron transfer involving charge separation followed by recombination.

DOI10.1002/chem.201503522