The 3D [(Cu2Br2){mu-EtS(CH2)(4)SEt}](n) material: a rare example of a coordination polymer exhibiting triplet-triplet annihilation
| Affiliation auteurs | !!!! Error affiliation !!!! |
| Titre | The 3D [(Cu2Br2){mu-EtS(CH2)(4)SEt}](n) material: a rare example of a coordination polymer exhibiting triplet-triplet annihilation |
| Type de publication | Journal Article |
| Year of Publication | 2016 |
| Auteurs | Bonnot A, Karsenti P-L, Juvenal F, Golz C, Strohmann C, Fortin D, Knorr M, Harvey PD |
| Journal | PHYSICAL CHEMISTRY CHEMICAL PHYSICS |
| Volume | 18 |
| Pagination | 24845-24849 |
| Date Published | SEP 28 |
| Type of Article | Article |
| ISSN | 1463-9076 |
| Résumé | EtS(CH2)(4)SEt, L1, forms with CuI a luminescent 2D polymer [Cu4I4{mu-L1}(2)](n) (CP1), which exhibits no triplet excitation energy migration, but with CuBr, it forms a 3D material (CP2), [(Cu2Br2){mu-L-1}](n) consisting of parallel (Cu2Br2S2)(n) layers bridged by L1's. CP2 shows T-1-T-1 annihilation at 298 K but not at 77 K. |
| DOI | 10.1039/c6cp04728a |