Crystal structure of bis(cyclohexylammonium) diphenyldioxalatostannate(IV)
| Affiliation auteurs | !!!! Error affiliation !!!! |
| Titre | Crystal structure of bis(cyclohexylammonium) diphenyldioxalatostannate(IV) |
| Type de publication | Journal Article |
| Year of Publication | 2015 |
| Auteurs | Sarr M, Diasse-Sarr A, Diop L, Plasseraud L, Cattey H |
| Journal | ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS |
| Volume | 71 |
| Pagination | 151+ |
| Date Published | FEB |
| Type of Article | Article |
| ISSN | 2056-9890 |
| Mots-clés | cis arrangement, Crystal structure, cyclohexylammonium, N-H center dot center dot center dot O hydrogen bonding, organotin(IV) compound, oxalate ligands |
| Résumé | Reaction of oxalic acid and diphenyltin dichloride in the presence of cyclohexylamine led to the formation of the title salt, (C6H14N)(2)[Sn(C6H5)(2)(C2O4)(2)]. The dianion is made up from an Sn(C6H5)(2) moiety cis-coordinated by two chelating oxalate anions, leading to an overall distorted octahedral coordination geometry of the Sn-IV atom. The negative charges are compensated by two surrounding cyclohexylammonium cations adopting chair conformations each. In the crystal, anions and cations are linked via a network of N-H center dot center dot center dot O hydrogen bonds into a layered arrangement parallel to (101). |
| DOI | 10.1107/S2056989014027716 |