Crystal structure of tricarbonyl(mu-diphenyl-phosphido-kappa P-2:P)(methyldiphenylsilyl-kappa Si) bis(triphenylphosphane-kappa P) iron(II) platinum(0)(Fe-Pt)
| Affiliation auteurs | !!!! Error affiliation !!!! |
| Titre | Crystal structure of tricarbonyl(mu-diphenyl-phosphido-kappa P-2:P)(methyldiphenylsilyl-kappa Si) bis(triphenylphosphane-kappa P) iron(II) platinum(0)(Fe-Pt) |
| Type de publication | Journal Article |
| Year of Publication | 2015 |
| Auteurs | Mohamed ASaid, Jourdain I, Knorr M, Rousselin Y, Kubicki MM |
| Journal | ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS |
| Volume | 71 |
| Pagination | 241+ |
| Date Published | FEB |
| Type of Article | Article |
| ISSN | 2056-9890 |
| Mots-clés | Crystal structure, diphenylmethylsilyl ligand, heterobimetallics, iron complexes, metalmetal bond, phosphido bridges, platinum complexes |
| Résumé | The title compound, [FePt(C12H10P)(C13H13Si)(C18H15P)(2)(CO)(3)] center dot 0.5CH(2)Cl(2), represents an example of a phosphido-bridged heterobimetallic silyl complex; these are interesting precursors for the coordination and activation of small unsaturated organic molecules. The mu(2)-PPh2 ligand spans the iron and platinum atoms, which are connected via a metal-metal bond of 2.7738 (4) angstrom. In contrast to most other complexes of the [(OC)(3)Fe(SiR3)(mu-PR2) PtL2] family, where the iron-bound SiR3 group is trans-arranged with respect to the mu(2)-PPh2 ligand, the SiPh2Me ligand is roughly collinear with the Fe-Pt vector [Si-Fe-Pt = 169.07 (3)degrees]. |
| DOI | 10.1107/S2056989015001565 |