P-Chirogenic Secondary Phosphine Oxides: New Stereoselective Synthesis and Applications
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Titre | P-Chirogenic Secondary Phosphine Oxides: New Stereoselective Synthesis and Applications |
Type de publication | Journal Article |
Year of Publication | 2015 |
Auteurs | Dutartre M, Bayardon J, Eymin M-J, Juge S |
Journal | PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS |
Volume | 190 |
Pagination | 955-956 |
Date Published | JUN 3 |
Type of Article | Article; Proceedings Paper |
ISSN | 1042-6507 |
Mots-clés | biarylphosphine oxides, P-chirogenic phosphine oxides, phosphinous acid boranes |
Résumé | A new stereoselective synthesis of P-chirogenic secondary phosphine oxides was described, by hydrolysis of aminophosphine borane prepared from ephedrine, then decomplexation. These compounds were used for the preparation of P-chirogenic diphosphine dioxides and biarylphosphine oxides, thanks to the aryne chemistry. |
DOI | 10.1080/10426507.2014.979992 |