P-Chirogenic Secondary Phosphine Oxides: New Stereoselective Synthesis and Applications

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TitreP-Chirogenic Secondary Phosphine Oxides: New Stereoselective Synthesis and Applications
Type de publicationJournal Article
Year of Publication2015
AuteursDutartre M, Bayardon J, Eymin M-J, Juge S
JournalPHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
Volume190
Pagination955-956
Date PublishedJUN 3
Type of ArticleArticle; Proceedings Paper
ISSN1042-6507
Mots-clésbiarylphosphine oxides, P-chirogenic phosphine oxides, phosphinous acid boranes
Résumé

A new stereoselective synthesis of P-chirogenic secondary phosphine oxides was described, by hydrolysis of aminophosphine borane prepared from ephedrine, then decomplexation. These compounds were used for the preparation of P-chirogenic diphosphine dioxides and biarylphosphine oxides, thanks to the aryne chemistry.

DOI10.1080/10426507.2014.979992