Crystal structure of bis(diisopropylammonium) molybdate
| Affiliation auteurs | !!!! Error affiliation !!!! |
| Titre | Crystal structure of bis(diisopropylammonium) molybdate |
| Type de publication | Journal Article |
| Year of Publication | 2018 |
| Auteurs | Sarr B, Mbaye A, Diop CAbdoul Kha, Melin F, Hellwig P, Sidibe M, Rousselin Y |
| Journal | ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS |
| Volume | 74 |
| Pagination | 1682+ |
| Date Published | NOV |
| Type of Article | Article |
| ISSN | 2056-9890 |
| Mots-clés | Crystal structure, graph set notation, molybdate anion, N-H center dot center dot center dot O hydrogen bonding, organic-inorganic salt |
| Résumé | The organic-inorganic title salt, (C6H16N)(2)[MoO4] or ((Pr2NH2)-Pr-i)(2)[MoO4], was obtained by reacting MoO3 with diisopropylamine in a 1:2 molar ratio in water. The molybdate anion is located on a twofold rotation axis and exhibits a slightly distorted tetrahedral configuration. In the crystal structure, the diisopropylammmonium ((Pr2NH2)-Pr-i)(+) cations and [MoO4](2-) anions are linked to each other through N-H center dot center dot center dot O hydrogen bonds, generating rings with R-12(12)(36) motifs that give rise to the formation of a three-dimensional network. The structure was refined taking into account inversion twinning (ratio of ca 4:1 between the two domains). |
| DOI | 10.1107/S2056989018014755 |