Aromatic Nucleophilic Substitution (SNAr) of meso-Nitroporphyrin with Azide and Amines as an Alternative Metal Catalyst Free Synthetic Approach To Obtain meso-N-Substituted Porphyrins

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TitreAromatic Nucleophilic Substitution (SNAr) of meso-Nitroporphyrin with Azide and Amines as an Alternative Metal Catalyst Free Synthetic Approach To Obtain meso-N-Substituted Porphyrins
Type de publicationJournal Article
Year of Publication2014
AuteursDevillers CH, Hebie S, Lucas D, Cattey H, Clement S, Richeter S
JournalJOURNAL OF ORGANIC CHEMISTRY
Volume79
Pagination6424-6434
Date PublishedJUL 18
Type of ArticleArticle
ISSN0022-3263
Résumé

Aromatic nucleophilic substitution reaction of the nitro group of meso-nitroporphyrins with azide and various amines was achieved and represents an alternative procedure to C-N coupling reactions usually needed to obtain such meso-N-substituted porphyrins in good yields.

DOI10.1021/jo5005586