Selective Preparation of Diamondoid Phosphonates

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TitreSelective Preparation of Diamondoid Phosphonates
Type de publicationJournal Article
Year of Publication2014
AuteursFokin AA, Yurchenko RI, Tkachenko BA, Fokina NA, Gunawan MA, Poinsot D, Dahl JEP, Carlson RMK, Serafin M, Cattey H, Hierso J-C, Schreiner PR
JournalJOURNAL OF ORGANIC CHEMISTRY
Volume79
Pagination5369-5373
Date PublishedJUN 6
Type of ArticleArticle
ISSN0022-3263
Résumé

We present an effective sequence for the preparation of phosphonic acid derivatives of the diamondoids diamantane, triamantane, [121]tetramantane, and [1(2,3)4-pentamantane. The reactions of the corresponding diamondoid hydroxy derivatives with PCl3 in sulfuric or trifluoroacetic acid give mono- as well as didichlorophosphorylated diamondoids in high preparative yields.
DOI10.1021/jo500793m