Water Adsorption in Flexible Gallium-Based MIL-53 Metal-Organic Framework
| Affiliation auteurs | !!!! Error affiliation !!!! |
| Titre | Water Adsorption in Flexible Gallium-Based MIL-53 Metal-Organic Framework |
| Type de publication | Journal Article |
| Year of Publication | 2014 |
| Auteurs | Coudert F-X, Ortiz AU, Haigis V, Bousquet D, Fuchs AH, Ballandras A, Weber G, Bezverkhyy I, Geolfroy N, Bellat J-P, Ortiz G, Chaplais G, Patarin J, Boutin A |
| Journal | JOURNAL OF PHYSICAL CHEMISTRY C |
| Volume | 118 |
| Pagination | 5397-5405 |
| Date Published | MAR 13 |
| Type of Article | Article |
| ISSN | 1932-7447 |
| Résumé | Understanding the adsorption of water in metal organic frameworks (MOF), and particularly in soft porous crystals, is a crucial prerequisite before considering MOFs for industrial applications. We report here a joint experimental and theoretical study on the behavior of a gallium-based breathing MOF, Ga-MIL-53, upon water adsorption. By looking at the energetics and thermodynamics of Ga-MIL-53, we demonstrate why it behaves differently from its sibling Al-MIL-53, showing a different phase at room temperature (a nonporous phase) and the presence of a hydrated narrow-pore structure at gas saturation pressure. Moreover, we present a complete water vapor pressure vs temperature phase diagram of Ga-MIL-53 upon water adsorption. |
| DOI | 10.1021/jp412433a |