P-Chirogenic Triazole-Based Phosphine: Synthesis, Coordination Chemistry, and Asymmetric Catalysis
| Affiliation auteurs | !!!! Error affiliation !!!! |
| Titre | P-Chirogenic Triazole-Based Phosphine: Synthesis, Coordination Chemistry, and Asymmetric Catalysis |
| Type de publication | Journal Article |
| Year of Publication | 2020 |
| Auteurs | Bayardon J, Rousselle B, Rousselin Y, Bonnin Q, Malacea-Kabbara R |
| Journal | EUROPEAN JOURNAL OF ORGANIC CHEMISTRY |
| Volume | 2020 |
| Pagination | 4723-4729 |
| Date Published | AUG 16 |
| Type of Article | Article |
| ISSN | 1434-193X |
| Mots-clés | asymmetric catalysis, Coordination chemistry, P-chirogenic phosphine, Stereoselective synthesis, Transition metals |
| Résumé | Herein we report the synthesis of a new P-chirogenic triazole-based phosphine according to the ephedrine methodology. Upon reaction with late transition-metal derivatives, Rh(I)and Pd-II, phosphine-triazole forms complexes with bidentate P,N coordination, as demonstrated by spectroscopic and X-ray crystallographic analyses. First experiments in asymmetric catalysis showed the catalytic potential of this new chiral P,N-type ligand. |
| DOI | 10.1002/ejoc.202000723, Early Access Date = {JUL 2020 |