Phosphido- and Amidozirconocene Cation-Based Frustrated Lewis Pair Chemistry

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TitrePhosphido- and Amidozirconocene Cation-Based Frustrated Lewis Pair Chemistry
Type de publicationJournal Article
Year of Publication2015
AuteursNormand AT, Daniliuc CG, Wibbeling B, Kehr G, Le Gendre P, Erker G
JournalJOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume137
Pagination10796-10808
Date PublishedAUG 26
Type of ArticleArticle
ISSN0002-7863
Résumé

{Methyl abstraction from neutral [Cp2ZrMe-(ERR')] complexes 1 (E = N, P; R, R' = alkyl, aryl) with either B(C6F5)(3) or [Ph3C][B(C6F5)(4)] results in the formation of [Cp2Zr(ERR')][X] complexes 2 (X- = MeB(C6F5)(3)(-), B-(C6F5)(4)(-)). The X-ray structure of amido complexes [Cp2Zr-(NPh2)][MeB(C6F5)(3)] (2d) and [Cp2Zr((NBuAr)-Bu-t)][B-(C6F5)(4)] (2e'

DOI10.1021/jacs.5b06551