Phosphido- and Amidozirconocene Cation-Based Frustrated Lewis Pair Chemistry
Affiliation auteurs | !!!! Error affiliation !!!! |
Titre | Phosphido- and Amidozirconocene Cation-Based Frustrated Lewis Pair Chemistry |
Type de publication | Journal Article |
Year of Publication | 2015 |
Auteurs | Normand AT, Daniliuc CG, Wibbeling B, Kehr G, Le Gendre P, Erker G |
Journal | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY |
Volume | 137 |
Pagination | 10796-10808 |
Date Published | AUG 26 |
Type of Article | Article |
ISSN | 0002-7863 |
Résumé | {Methyl abstraction from neutral [Cp2ZrMe-(ERR')] complexes 1 (E = N, P; R, R' = alkyl, aryl) with either B(C6F5)(3) or [Ph3C][B(C6F5)(4)] results in the formation of [Cp2Zr(ERR')][X] complexes 2 (X- = MeB(C6F5)(3)(-), B-(C6F5)(4)(-)). The X-ray structure of amido complexes [Cp2Zr-(NPh2)][MeB(C6F5)(3)] (2d) and [Cp2Zr((NBuAr)-Bu-t)][B-(C6F5)(4)] (2e' |
DOI | 10.1021/jacs.5b06551 |