Crystal structure of the bis(cyclohexylammonium) succinate succinic acid salt adduct

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TitreCrystal structure of the bis(cyclohexylammonium) succinate succinic acid salt adduct
Type de publicationJournal Article
Year of Publication2015
AuteursSarr M, Diasse-Sarr A, Diop L, Plasseraud L, Cattey H
JournalACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
Volume71
Pagination899+
Date PublishedAUG
Type of ArticleArticle
ISSN2056-9890
Mots-clésCrystal structure, cyclohexylammonium cation, hydrogen bonds, molecular adduct, organic salt, succinate, succinic acid
Résumé

The crystal structure of the title salt adduct, 2C(6)H(14)N(+)center dot C4H4O42-center dot C4H6O4, consists of two cyclohexylammonium cations, one succcinate dianion and one neutral succinic acid molecule. Succinate dianions and succinic acid molecules are self-assembled head-to-tail through O-H center dot center dot center dot O hydrogen bonds and adopt a syn-syn configuration, leading to a strand-like arrangement along [101]. The cyclohexylammonium cations have a chair conformation and act as multidentate hydrogen-bond donors linking adjacent strands through intermolecular NH center dot center dot center dot O interactions to both the succinate and the succinic acid components. This results in two-dimensional supramolecular layered structures lying parallel to (010).

DOI10.1107/S2056989015012621