Conformational landscape of the SF6 dimer as revealed by various free jet conditions
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Titre | Conformational landscape of the SF6 dimer as revealed by various free jet conditions |
Type de publication | Conference Paper |
Year of Publication | 2019 |
Auteurs | Gaveau M.A, Mons M., Bruel L., Potapov A., Turner A.C, Boudon V., Asselin P. |
Editor | Zhang Y, Emerson DR, Lockerby D, Wu L |
Conference Name | 31ST INTERNATIONAL SYMPOSIUM ON RAREFIED GAS DYNAMICS (RGD31) |
Publisher | James Weir Fdn; USA AF Off Sci Res; Glasgow City Council; UK Engn & Phys Sci Res Council |
Conference Location | 2 HUNTINGTON QUADRANGLE, STE 1NO1, MELVILLE, NY 11747-4501 USA |
ISBN Number | 978-0-7354-1874-5 |
Résumé | The experiment SPIRALES coupling a tunable infrared laser to a pulsed supersonic free jet has allowed us to reinvestigate the high-resolution absorption spectroscopy of the SF6 dimer in the v3 mode region under various experimental conditions. In addition to the SF6 dimer spectrum so far reported, we demonstrate the existence of two new spectral features: i) one assigned to a second conformer of this species, characterized by a larger interatomic distance as well as ii) a complex (SF6)(2)-He. |
DOI | 10.1063/1.5119529 |