Bi4V2O11 and BITAVOX.20 coatings deposited by reactive magnetron sputtering
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Titre | Bi4V2O11 and BITAVOX.20 coatings deposited by reactive magnetron sputtering |
Type de publication | Journal Article |
Year of Publication | 2015 |
Auteurs | Dereeper E., Briois P., Vannier R.-N, Billard A. |
Journal | MATERIALS CHEMISTRY AND PHYSICS |
Volume | 153 |
Pagination | 9-16 |
Date Published | MAR 1 |
Type of Article | Article |
ISSN | 0254-0584 |
Mots-clés | Crystal structure, Electrochemical techniques, Oxides, Physical vapour deposition, Thin films |
Résumé | Bi4V2O11 and BITAVOX.20 films were deposited by magnetron sputtering in reactive conditions from Bi, V and Ta metallic targets. The influence of sputtering conditions on the films composition was studied and then a structural study at variable temperature was carried out. Before annealing, the films were amorphous and the gamma-Bi4V2O11 structure was obtained for a treatment at temperatures over 550 degrees C whereas BITAVOX.20 started to crystallise at 425 degrees C. In both cases, crystallisation occurred via an intermediate fluorite phase presenting a tetragonal deformation as already observed for other compounds with the Aurivillius structure. (C) 2014 Elsevier B.V. All rights reserved. |
DOI | 10.1016/j.matchemphys.2014.12.021 |