Triterpene saponins of the root bark of Olax obtusifolia De Wild

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TitreTriterpene saponins of the root bark of Olax obtusifolia De Wild
Type de publicationJournal Article
Year of Publication2018
AuteursPertuit D, Mitaine-Offer A-C, Miyamoto T, Tanaka C, Delaude C, Lacaille-Dubois M-A
JournalPHYTOCHEMISTRY LETTERS
Volume28
Pagination174-178
Date PublishedDEC
Type of ArticleArticle
ISSN1874-3900
Mots-clés2D NMR, ESI-MS, Olacaceae, Olax obtusifolia, Triterpene saponins
Résumé

Four undescribed triterpenoid saponins together with five known and oleanolic acid were isolated from root bark of Olax obtusifolia De Wild. Their structures were elucidated by spectroscopic methods including 1D and 2D NMR experiments, in combination with mass spectrometry as 3-O-alpha-L-rhamnopyranosyl-(1 -> 4)-alpha-L-rhamnopyranosyl-(1 -> 3)-beta-D-glucuronopyranosyloleanolic acid, 3-O-alpha-L-rhamnopyranosyl-(1 -> 4)-alpha-L-rhamnopyranosyl-(1 -> 3)-beta-D-glucuronopyranosyloleanolic acid 28-O-beta-D-glucopyranosyl ester, 3-O-alpha-L-rhamnopyranosyl-(1 -> 3)-beta-D-glucopyranosyl-(1 -> 2)-[beta-D glucopyranosyl (1 -> 3)]-beta-D-glucuronopyranosyloleanolic acid and 3-O-alpha-L-rhamnopyranosyl-(1 -> 3)-beta-D-glucopyranosyl-(1 -> 2)-[beta-D glucopyranosyl-(1 -> 3)]-beta-D-glucuronopyranosyloleanolic acid 28-O-beta-D-glucopyranosyl ester.

DOI10.1016/j.phytol.2018.09.018