First high resolution analysis of the v(3) band of the (SF6)-S-36 isotopologue

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TitreFirst high resolution analysis of the v(3) band of the (SF6)-S-36 isotopologue
Type de publicationJournal Article
Year of Publication2018
AuteursFaye M., Manceron L., Roy P., Boudon V., Loete M.
JournalJOURNAL OF MOLECULAR SPECTROSCOPY
Volume346
Pagination23-26
Date PublishedAPR
Type of ArticleArticle
ISSN0022-2852
Résumé

The v(3) band of the (SF6)-S-36 isotopologue has been recorded in natural abundance (0.02%) at 153 K-temperature with doppler limited resolution, using a Fourier transform spectrometer. For the first time, the high resolution analysis of this band is performed thanks to the Dijon tensorial formalism model. The effective Hamiltonian parameters are determined and the interest of studying rare SF6 isotopologues is discussed. (C) 2018 Elsevier Inc. All rights reserved.

DOI10.1016/j.jms.2018.01.002