Tetracationic and Tetraanionic Manganese Porphyrins: Electrochemical and Spectroelectrochemical Characterization

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TitreTetracationic and Tetraanionic Manganese Porphyrins: Electrochemical and Spectroelectrochemical Characterization
Type de publicationJournal Article
Year of Publication2017
AuteursJiang X, Gros CP, Chang Y, Desbois N, Zeng L, Cui Y, Kadish KM
JournalINORGANIC CHEMISTRY
Volume56
Pagination8045-8057
Date PublishedJUL 17
Type of ArticleArticle
ISSN0020-1669
Résumé

{The electrochemistry and spectroelectrochemistry of four tetrapositively charged and two tetranegatively charged porphyrins were characterized in two nonaqueous solvents (dimethyl sulfoxide and N,N-dimethylformamide) containing 0.1 M tetra-n-butylammonium perchlorate. The tetrapositively charged compounds are represented by the tetrapyridylporphyrins [TRPyPM](4+)(X-)(4), where R is a methyl or [2-[2-(2-methoxy)ethoxy]ethoxy]ethyl group

DOI10.1021/acs.inorgchem.7b00732