A general diastereoselective synthesis of highly functionalized ferrocenyl ambiphiles enabled on a large scale by electrochemical purification
| Affiliation auteurs | !!!! Error affiliation !!!! |
| Titre | A general diastereoselective synthesis of highly functionalized ferrocenyl ambiphiles enabled on a large scale by electrochemical purification |
| Type de publication | Journal Article |
| Year of Publication | 2017 |
| Auteurs | Lerayer E, Renaut P, Roger J, Pirio N, Cattey H, Devillers CH, Lucas D, Hierso J-C |
| Journal | CHEMICAL COMMUNICATIONS |
| Volume | 53 |
| Pagination | 6017-6020 |
| Date Published | JUN 4 |
| Type of Article | Article |
| ISSN | 1359-7345 |
| Résumé | A general synthesis of highly functionalized ferrocenes, which include (P,B)- and (N,B)-ambiphiles, has been developed at a multigram scale. Diastereoselective stepwise modification of di-tert-butylated ferrocenes included the unprecedented separation of electroactive species. Bulky alkyl groups on ferrocenes ensure planar chirality of ambiphiles and enforce closer proximity of antagonist Lewis functions. |
| DOI | 10.1039/c7cc02469j |