Gallium(III) and Indium(III) Complexes with meso-Monophosphorylated Porphyrins: Synthesis and Structure. A First Example of Dimers Formed by the Self-Assembly of meso-Porphyrinylphosphonic Acid Monoester
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Titre | Gallium(III) and Indium(III) Complexes with meso-Monophosphorylated Porphyrins: Synthesis and Structure. A First Example of Dimers Formed by the Self-Assembly of meso-Porphyrinylphosphonic Acid Monoester |
Type de publication | Journal Article |
Year of Publication | 2017 |
Auteurs | Enakieva YYu., Volostnykh MV, Nefedov SE, Kirakosyan GA, Gorbunova YG, Tsivadze AYu., Bessmertnykh-Lemeune AG, Stern C, Guilard R |
Journal | INORGANIC CHEMISTRY |
Volume | 56 |
Pagination | 3055-3070 |
Date Published | MAR 6 |
Type of Article | Article |
ISSN | 0020-1669 |
Résumé | The synthesis and structural characterization, both in solution by means of H-1 and P-31 NMR and UV-vis spectroscopies and in the solid state by X-ray diffraction on single crystal, of a series of gallium(III) and indium(III) meso-mono(diethoxyphosphoryl)porphyrins bearing different peripheral substituents as well as the corresponding monoesters and phosphonic acids are reported. This work describes the first example of the X-ray structure of a self-assembled dimer formed via strong binding between the oxygen atom of the phosphonate substituent and the gallium(III) cations of adjacent porphyrin molecules [Ga-O = 1.9708(13) angstrom]. |
DOI | 10.1021/acs.inorgchem.6b03160 |