Organotin(IV) scorpionates - X-ray structure and crystal packing of TpSn(Cl)(2) (n-Bu) [Tp = hydrotris(pyrazol-1-yl)borate]
Affiliation auteurs | !!!! Error affiliation !!!! |
Titre | Organotin(IV) scorpionates - X-ray structure and crystal packing of TpSn(Cl)(2) (n-Bu) [Tp = hydrotris(pyrazol-1-yl)borate] |
Type de publication | Journal Article |
Year of Publication | 2016 |
Auteurs | Lange J, Cattey H, Plasseraud L |
Journal | MAIN GROUP METAL CHEMISTRY |
Volume | 39 |
Pagination | 125-129 |
Date Published | AUG |
Type of Article | Article |
ISSN | 0792-1241 |
Mots-clés | coordination complex, N-ligand, polypyrazolylborates, Self-assembly, TiN, X-ray crystallography |
Résumé | {Reaction of potassium hydrotris(pyrazol-1-yl) borate (KTp) and n-BuSnCl3 at room temperature led to the quantitative formation of TpSn(Cl)(2)(n-Bu) (1). Colorless single crystals were obtained from a mixture of toluene/dichloromethane and were characterized as TpSn(Cl)(2)(nBu)(center dot 1/2) toluene. Complex 1 crystallizes in the triclinic P (1) over bar space group, with Z = 2 |
DOI | 10.1515/mgmc-2016-0018 |