Organotin(IV) scorpionates - X-ray structure and crystal packing of TpSn(Cl)(2) (n-Bu) [Tp = hydrotris(pyrazol-1-yl)borate]

Affiliation auteurs!!!! Error affiliation !!!!
TitreOrganotin(IV) scorpionates - X-ray structure and crystal packing of TpSn(Cl)(2) (n-Bu) [Tp = hydrotris(pyrazol-1-yl)borate]
Type de publicationJournal Article
Year of Publication2016
AuteursLange J, Cattey H, Plasseraud L
JournalMAIN GROUP METAL CHEMISTRY
Volume39
Pagination125-129
Date PublishedAUG
Type of ArticleArticle
ISSN0792-1241
Mots-cléscoordination complex, N-ligand, polypyrazolylborates, Self-assembly, TiN, X-ray crystallography
Résumé

{Reaction of potassium hydrotris(pyrazol-1-yl) borate (KTp) and n-BuSnCl3 at room temperature led to the quantitative formation of TpSn(Cl)(2)(n-Bu) (1). Colorless single crystals were obtained from a mixture of toluene/dichloromethane and were characterized as TpSn(Cl)(2)(nBu)(center dot 1/2) toluene. Complex 1 crystallizes in the triclinic P (1) over bar space group, with Z = 2

DOI10.1515/mgmc-2016-0018